William
Kovarik |
Fuels and Society C: 7. Reformulated Gasolines |
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When tetraethyllead was
taken off the US market in the 1970s, oil refiners had a
number of options to increase the octane value of
gasoline. Outside of refinery operations (See Refining) oil companies could add
blends of octane boosting compounds from external
sources. The external option involved adding "oxygenated" fuels, which include alcohols like methanol, ethanol and tertiary butyl alcohol (TBA) and ether combinations, especially MTBE (methyl tertiary butyl ether). Ethanol can be made from farm products or cellulosic biomass. Methanol, MTBE and TBA are usually made from natural gas. The oil industry usually preferred TBA and MTBE over alcohol blends because they were somewhat easier to handle. Ethanol was also seen as a competitor for profits and has long been resisted by the oil industry (See Back to Ethanol). Along with boosting octane, oxygenated fuels have lower emissions of HC and CO, and have been used to fight city smog since the late 1980s, when Denver and Phoenix made them mandatory in city gasoline pumps. The idea of expanding the program by using ethanol blends became part of the 1990 Clean Air Act that President George Bush sent to Congress in 1990. The oil industry offered reformulated gasolines (RFG) as a substitute for most of the ethanol provisions in the Act. The idea was to reduce pollutants such as hydrocarbons, toxics (from aromatics), and nitrogen oxides. When compared to typical gasoline , the EPA estimated that RFG reduced hydrocarbon emissions by at least 15% in major cities and cut back on the cancer risk from gasolines with high benzene content. RFG was somewhat different from previous gasohol and MTBE blends because it evaporated less readily (it had lower vapor pressure) and lower benzene and sulfur content. Gasoline, Gasohol, MTBE blends and
RFG
* Oxygenate concentrations shown are for separate batches of fuel; combinations of both MTBE and ethanol in the same blend can never be above 15 volume percent total. The MTBE Reformulated Gasoline dilemma is a good example of the law of unintended consequences. While solving air pollution problems, MTBE created serious water pollution problems and has been banned from at least 13 states. (see MTBE). One solution is for the federal government to remove the requirement that RFG contain oxygenated fuels In other words, to no longer require ethanol or MTBE. RFG would still have lower vapor pressure, benzene and sulfur, but the cost would be higher and the air pollution benefit of the oxygen would be lost. The other solution is to require the use of ethanol rather than MTBE or ethanol. Although feasible, there are technical issues which need to be examined. (See Back to Ethanol). EPA Information on RFG About reformulated gasolines http://www.epa.gov/otaq/consumer/fuels/oxypanel/epa/index.htm Origin of RFG program http://www.epa.gov/otaq/rfgorig.htm Is RFG a new gasoline ? http://www.epa.gov/otaq/rfgnew.htm Air pollution and history of RFG |
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